一、基金项目

1. 国家自然科学基金面上项目，No. 22078217，电控离子膜分离/催化耦合系统的构建及其传质反应协同机制，主持，2021-2024

2. 青海盐湖工业股份有限公司科技计划项目，基于超高镁锂比盐湖卤水提锂的高性能电控离子膜分离技术子课题，主持，2021-2024

3. 中国辐射防护研究院自主科研项目，电控离子膜分离技术处理含铀废水，主持，2023-2024

4. 山西省应用化学研究所科研项目，电控离子交换膜分离装置的试制，主持，2020-2022

5. 国家自然科学基金青年基金项目，No. 21706181，电势振荡锂离子筛分膜的有序组装及离子传递双通道耦合传质机制，主持，2018-2020

二、代表性论文

1. Yasi Hu, Qinglong Luo, Xiao Du*, Jun Li*, Xiaogang Hao, Film electrode by incorporating polypyrrole/carbon black into cross-linked binders of chitosan/cationic polyacrylamide for selective chloride extraction in wastewater, Separation and Purification Technology, 330 (2024) 125434.

2. Jiahui Ren, Yongping He, Haidong Sun, Rongzi Zhang, Juan Li, Wenbiao Ma, Zhong Liu, Jun Li, Xiao Du*, Xiaogang Hao*, Construction of nitrogen-doped carbon cladding LiMn2O4 film electrode with enhanced stability for electrochemically selective extraction of lithium ions, Frontiers of Chemical Science and Engineering, 17 (2023) 2050-2060.

3. Liang Zhang, Zhen Ma, Haidong Sun, Rongzi Zhang, Zilong Zhao, Jie Wang, Zhonglin Zhang, Zhong Liu, Jun Li, Xiao Du*, Xiaogang Hao*, A novel CNTs/QCS/BiOBr composite membrane with electron-ion transfer channel for Br- recovery in ESIX process, Journal of Colloid and Interface Science, 646 (2023) 784-793.

4. Dandan Xu, Bing Zhao, Qinglong Luo, Xiao Du*, Xiaogang Hao, Zhong Liu*, Acid promoted activity of UiO-66 as an efficient adsorbent for boron removal from aqueous solution, Separation and Purification Technology, 317 (2023) 123855.

5. Zheng Zhang, Jinfeng Zhang, Zhihua Zhang, Xiao Du*, Xiaogang Hao*, Xiaowei An, Guoqing Guan*, Jun Li, Zhong Liu, Cross-linked PVDF-b-PAA composite binder enhanced LiMn2O4/C film based electrode for selective extraction of lithium from brine with a high Mg/Li ratio, Separation and Purification Technology, 316 (2023) 123777.

6. Jie Qiao, Wenbiao Ma, Xiao Du*, Xuli Ma, Zhong Liu, Jun Li, Guoqing Guan*, Abuliti Abudula, Xiaogang Hao*, ZIF-8 derived carbon with confined sub-nanometer pores for electrochemically selective separation of chloride ions, Separation and Purification Technology, 295 (2022) 121222.

7. Dongcheng Lin, Huixin Zhang, Xiaowei An, Lutong Chang, Ayman Alameen, Shengqi Ding, Xiao Du*, Xiaogang Hao*, Theoretical calculation assisted materials screening of BiOX (X = F, Cl, Br, I) for electrochemical absorption of cesium ions, Physical Chemistry Chemical Physics, 23 (2021) 8500-8507.

8. Zheng Zhang, Xiao Du*, Qiang Wang, Fengfeng Gao, Tongtong Jin, Xiaogang Hao*, Pengfei Ma, Jun Li, Guoqing Guan, A scalable three-dimensional porous λ-MnO2/rGO/Ca-alginate composite electroactive film with potential-responsive ion-pumping effect for selective recovery of lithium ions, Separation and Purification Technology, 259 (2021) 118111.

9. Wenbiao Ma, Xiao Du*, Mimi Liu, Fengfeng Gao, Xuli Ma, Yongguo Li, Guoqing Guan, Xiaogang Hao*, A Conductive Chlorine Ion-Imprinted Polymer Threaded in Metal-Organic Frameworks for Electrochemically Selective Separation of Chloride Ions, Chemical Engineering Journal, 412 (2021) 128576.

10. Tian Chen, Peifen Wang, Xiao Du*, Fengfeng Gao, Xuli Ma, Feifan Liu, Ayman Alameen, Keyong Tang, Xiaogang Hao**, A novel hexagonal prism Cu-BTC by unipolar pulse electropolymerization, Materials Letters, 254 (2019) 137-140.

11. Qiang Wang, Xiao Du*, Fengfeng Gao, Feifan Liu, Mimi Liu, Xiaogang Hao**, Keyong Tang, Guoqing Guan, Abuliti Abudula, A novel H1.6Mn1.6O4/reduced graphene oxide composite film for selective electrochemical capturing lithium ions with low concentration, Separation and Purification Technology, 226 (2019) 59-67.

12. Mimi Liu, Xiao Du*, Fengfeng Gao, Jinhua Luo, Qiang Wang, Feifan Liu, Lutong Chang, Xiaogang Hao**, A novel potential oscillation in situ removal method: preparation of ion imprinted 8-HQ/PPy film for the selective separation of zinc ions, Journal of Solid State Electrochemistry, 23 (2019) 2541-2550.

13. Qianyao Shen, Xiao Du*, Fengfeng Gao, Lutong Chang, Zhonglin Zhang, Xuli Ma, Xiaogang Hao**, Keyong Tang, BiOCl-Coated Electroactive Film for Potential-Triggered Selective Removal of Cesium Ions from Simulated Wastewater, Industrial & Engineering Chemistry Research, 58 (2019) 12816-12824.

14. Huixin Zhang, Xiao Du*, Shengqi Ding, Qiang Wang, Lutong Chang, Xuli Ma, Xiaogang Hao**, Changjun Pen, DFT calculations of the synergistic effect of λ-MnO2/graphene composites for electrochemical adsorption of lithium ions, Physical Chemistry Chemical Physics, 21 (2019) 8133-8140.

15. Huixin Zhang, Ayman Alameen, Xiaowei An, Qianyao Shen, Lutong Chang, Shengqi Ding, Xiao Du*, Xuli Ma, Xiaogang Hao*, Changjun Peng, Theoretical and experimental investigations of BiOCl for electrochemical adsorption of cesium ions, Physical Chemistry Chemical Physics, 21 (2019) 20901-20908.

16. Xiao Du, Di Zhang, Xuli Ma, Wenlei Qiao, Zhongde Wang, Xiaogang Hao*, Guoqing Guan**, Electrochemical redox induced rapid uptake/release of Pb(II) ions with high selectivity using a novel porous electroactive HZSM-5@ PANI/PSS composite film, Electrochimica Acta, 282 (2018) 384-394.

17. Xiao Du, Xuli Ma, Pengle Zhang, Junlan Zheng, Zhongde Wang, Fengfeng Gao, Xiaogang Hao*, Shibin Liu, Guoqing Guan**, A novel electric-field-accelerated ion-sieve membrane system coupling potential-oscillation for alkali metal ions separation, Electrochimica Acta, 258 (2017) 718-726.

18. Xiao Du, Quan Zhang, Wenlei Qiao, Xiaolong Sun, Xuli Ma, Xiaogang Hao*, Zhongde Wang, Abuliti Abudula, Guoqing Guan, Controlled self-assembly of oligomers-grafted fibrous polyaniline/single zirconium phosphate nanosheet hybrids with potential-responsive ion exchange properties, Chemical Engineering Journal, 302 (2016) 516-525.

19. Xiao Du, Guoqing Guan*, Xiumin Li, Ajay D. Jagadale, Xuli Ma, Zhongde Wang, Xiaogang Hao*, Abuliti Abudula, A novel electroactive λ-MnO2/PPy/PSS core-shell nanorod coated electrode for selective recovery of lithium ions at low concentration, Journal of Materials Chemistry A, 4 (2016) 13989-13996.

20. Xiao Du, Xiaogang Hao*, Zhongde Wang, Guoqing Guan*, Electroactive ion exchange materials: current status in synthesis, applications and future prospects, Journal of Materials Chemistry A, 4 (2016) 6236-6258.

21. Xiao Du, Xiaolong Sun, Hao Zhang, Zhongde Wang, Xiaogang Hao*, Guoqing Guan**, Abuliti Abudula, A Facile Potential-Induced In-Situ Ion Removal Trick: Fabrication of High-Selective Ion-Imprinted Film for Trivalent Yttrium Ion Separation, Electrochimica Acta, 176 (2015) 1313-1323.

22. Xiao Du, Hao Zhang, Xiaogang Hao*, Guoqing Guan*, Abuliti Abudula, Facile Preparation of Ion-Imprinted Composite Film for Selective Electrochemical Removal of Nickel(II) Ions, ACS Applied Materials & Interfaces, 6 (2014) 9543-9549.

23. Xiao Du, Xiaogang Hao*, Zhongde Wang, Xuli Ma, Guoqing Guan**, Abudula Abuliti, Guozhang Ma, Shibin Liu, Highly stable polypyrrole film prepared by unipolar pulse electro-polymerization method as electrode for electrochemical supercapacitor, Synthetic Metals, 175 (2013) 138-145.

三、授权专利

1. 郝晓刚, 郝晓琼, 杜晓, 张忠林, Method and device for removing chloride ion in desulfurized wastewater by electrochemical coupling, 美国，US11661356 B2

2. 郝晓刚, 郝晓琼, 杜晓, 张忠林, 一种连续高效资源化处理工业废水中氯离子的装置, 中国，ZL201921003772.5

2. 郝晓刚, 杜晓, 刘长林, 李春成, 一体式分凝器及其应用, 中国，ZL201710170863.7

3. 郝晓刚, 杜晓, 蔡富刚, 郑君兰, 张忠林, 张兴芳, 高凤凤, 一种连续电控离子分离装置和工艺, 中国，ZL201610487444.1

4. 郝晓刚, 杜晓, 张权, 官国清, 张忠林, 马旭莉, 薛春峰, 孙晓龙, 一种合成无定形聚苯胺/磷酸锆复合膜的方法, 中国，ZL201410526742.8

四、出版专著

电控离子交换技术及应用, 化学工业出版社, 2017.08